Opt for the Easy Way: Determining Glycerol in Biodiesel Using Ion Chromatography

Current US and European standards stipulate gas chromatography to determine the glycerol content in biodiesel. However, this method is both tedious and rather expensive. Metrohm recommends ion chromatography (IC) as a simple, cost-efficient and highly accurate alternative.

The free and total content of glycerol in vegetable oil methyl esters (biodiesel) is of paramount importance for the quality of biodiesel. Both free and bonded glycerols (= total glycerol) lead to severe operational problems such as injector deposits and filter clogging.

The US ASTM D 6751 and the European EN 14214 specify a maximum total glycerol content of 2400 ppm (0.24%) and 2500 ppm (0.25%), respectively. The maximum free glycerol content is limited to 200 ppm (0.02%) in both standards, which stipulate gas chromatographic (GC) analysis involving time- and reagent-consuming derivatisations. In addition, GC methods encounter coelution problems with biodiesel samples produced from or containing lauric oils, such as coconut and palm kernel oil.