Analytical Instrumentation

Higher DHA Sample Throughput for PONA Analysis: Options for Helium and Hydrogen

Author: Barry Burger on behalf of Restek Corp

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Accurate information about the concentrations of the individual components in gasolines is critical for evaluating raw materials and controlling refinery processes. A high-resolution GC method for detailed hydrocarbon analysis (DHA) of gasolines is outlined in American Society of Testing and Materials (ASTM) Method D6730-01?often referred to as the PONA (paraffins, olefins, naphthenes, aromatics) or PIANO (paraffins, isoparaffins, aromatics, naphthenes, olefins) analysis. ASTM D6730-01 is specific for the analysis of these hydrocarbon components, plus oxygenated additives such as methanol, ethanol, tert-butanol, methyl tert-butyl ether (MTBE), and tert-amyl methyl ether (TAME) in spark-ignition engine fuels.

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